Suevites from the Azuara and Rubielos de la Cérida (Spain) impact structures

Suevite occurrences in the Spanish impact structures

Suevites in the Spanish impact structures in an up to 10 km thick sedimentary target have so far been found in two different outcrop situations:

— as the so-called basal breccia in the Azuara structure and the Rubielos de la Cérida impact basin and

— as large blocks quarried out from a megabreccia in the Rubielos de la Cérida basin.

The name basal breccia refers to its stratigraphic position at the base of the undisturbed post-impact (and post-Alpidic) layers. The polymictic and rather heterogeneous breccia is up to c. 20 m thick and is found in many parts of the Azuara and Rubielos de la Cérida structures unconformably overlying the Alpidicly folded and impact-deformed sediments of the Iberian System (Fig. 1).

suevite (basal breccia) unconformity; central-uplift chain, Rubielos de la Cérida impact basinFig. 1. Suevite (basal breccia)  unconformably overlying steeply dipping Jurassic limestones. Central uplift chain in the Rubielos de la Cérida basin.

Both Paleozoic and Mesozoic rocks contribute to the matrix-supported breccia components which are angular to sharp-edged, but well-rounded components are also observed. Frequently, they show distinct reaction seams in contact with the matrix. Breccia generations (breccias-within-breccias) are abundant. The sharp-edged clasts, especially the limestone fragments, suggest an immediate embedding after the brecciation and mixing of the Paleozoic and Mesozoic components. Breccia specimens break into pieces across the clast boundaries due to the extremely hard matrix and an exceptional cementation.

The matrix is composed of calcite and (from X-ray fluorescence analysis) up to 10 % Si02. X-ray diffraction analysis and thin-section inspection with strong magnification, however, could only identify minute traces of quartz and silicates (e.g., mica). The major fraction of the Si02 content is thus expected to be in an amorphous phase finely dispersed within the breccia matrix. In rare cases, however, tiny glass fragments (see Fig. 4) can be observed in thin sections of the basal-breccia matrix, and we assume that the amorphous phase is glass, too. This would well fit a model by Kieffer & Simonds (1980) which explains the obvious absence of impact melt sheets in and around craters from sedimentary targets. The authors conclude that the large amount of shock-produced volatiles (from pore-water vaporization and limestone decarbonization) in sedimentary targets prevents melt-sheet formation and, instead, finely disperses the shock-melted material.

We further note that thin sections show shock-metamorphic effects in the form of PDFs and PFs in quartz as well as diaplectic quartz. Thus, the basal breccia as a polymictic breccia with glass components and mineral clasts displaying shock metamorphism, is a typical suevite or suevite breccia.

The question arises whether the basal breccia may alternatively be considered an impact melt rock (according to the IUGS nomenclature; see discussion here: https://www.impact-structures.com/impactmeltpage.html ) that by definition has a matrix solidified from a shock-produced melt. In the Azuara/Rubielos de la Cérida case this would apply if the basal-breccia matrix had predominantly crystallized from a carbonate melt. Here we note that components of the basal breccia are regularly observed (see images below) to have undergone partial up to nearly complete decomposition which is obviously connected with flow texture of the basal breccia matrix. These zones were analyzed in detail by Katschorek (1990), and she was able to establish the presence of former carbonate melt. For the time being, the true character of the basal breccia impactite remains subject for discussion.

 

The Cucalón (Azuara impact) suevites

massive suevite deposit near Cucalón exhibiting platy jointing, Azuara impact structureFig. 2. Massive outcrop of the Cucalón fine-grained suevite (basal breccia). Note the steeply dipping platy jointing which has possibly originated from cooling of the suevite body.

clast-rich suevite polymictic impact breccia, Cucalón deposit, Azuara impact structureFig. 3. Suevite (basal breccia) near Cucalón, Azuara structure. – Geologists from the Zaragoza university considered the Cucalón suevites a normal lacustrine limestone they had allegedly drilled near Nombrevilla roughly 10 km off the Cucalón deposit.

suevite basal impact breccia, Cucalón deposit, Azuara impact structureFig. 4. Suevite (basal breccia) near Cucalón, Azuara structure. Maximum size is 18 cm.

glass particle in suevite, photomicrograph, Cucalón deposit, Azuara impact structureFig. 5. Glass in the Cucalón suevite (basal breccia). Within a carbonate matrix, the glass fragment with fluidal texture is located in a small void lined by calcite crystals. Photomicrograph: xx nicols and plane light; the field is 240 µm wide.

suevite impact breccia, relics of carbonate melt, Cucalón deposit, Azuara impact structureFig. 6. Suevite (basal breccia) near Cucalón. Note the flow texture and the whitish matrix material which may be crystallized carbonate melt. 12 cm maximum horizontal size.

suevite, relics of carbonate melt, Cucalón deposit, Azuara impact structureFig. 7. Suevite (basal breccia) near Cucalón, Azuara structure. The diffuse, clast-free whitish matrix material may be former carbonate melt. 16 cm.

suevite, brownish variety, Cucalón, Azuara impact structureFig. 8. Suevite (basal breccia) near Cucalón. Brownish variety with rare larger clasts. 10.5 cm maximum horizontal size.

suevite, fine-grained variety, Cucalón, Azuara impact structure

Fig. 9. Suevite (basal breccia) near Cucalón, fine-grained variety; close-up see below. 14 cm maximum size. Many clasts have an accretionary lapilli appearance.

suevite, fine-grained variety, detail; Cucalón, Azuara impact structure

Fig. 10. Suevite, fine-grained variety, detail; the field is 2.5 cm wide. Note the many well-rounded clasts, flow texture and the obscure grayish/whitish matrix material. The matrix is assumed to result from decarbonization/melting and recombination/crystallization of carbonate target rocks and, in the strict sense, this variety could be an impact melt rock. Also note the accretionary lapillistone texture.

suevite, fine-grained variety 2; Cucalón, Azuara impact structure

Fig. 11. Another variety of the fine-grained Cucalón suevite with a reddish matrix and only very small-sized clasts grading into the matrix and reminding of a lapillistone. 10.5 cm maximum size of the sample.

 

The Portillo-Fuendetodos and Almonacid de la Cuba (Azuara impact) suevites

suevite, Fuendetodos variety, Azuara impact structureFig. 12. Suevite, Azuara impact structure (Spain); Portillo variety, S Fuendetodos. Note the ghost fragments and the rudimentary black limestone clast suggesting outflow of melted material. A microscopic investigation of this whitish material by Tanja Katschorek revealed a composition of carbonate microlites in the form of needle-shaped crystallites grown in tufts, and dendritic crystallites, typical of crystallized carbonate melt.

photomicrograph of the Fuendetodos suevite variety, Azuara impact structureFig. 13. Suevite, Azuara impact structure (Spain); Portillo variety, S Fuendetodos. Note the porphyritic texture of the clastic matrix. Photomicrograph (by courtesy of T. Kar´tschorek), the field is 2 mm wide.

suevite from the northern rim region, Azuara impact structure near FuendetodosFig. 14. Suevite from the Azuara impact structure; Almonacid de la Cuba variety. The white matrix material is assumed to be relics of carbonate melt.

suevite breccia, Portillo variety, Azuara impact structureFig. 15. Suevite, Azuara impact structure (Spain); Portillo variety, S Fuendetodos. Note the grading, the flow adjustment and the temperature-induced reddish color of many clasts typical of numerous suevites from the Azuara and Rubielos de la Cérida impacts.

peculiar suevite breccia, Portillo variety from near Fuendetodos, Azuara impactFig. 16. Suevite, Azuara impact structure (Spain); another sample of the Portillo variety, S Fuendetodos. Note the peculiar mixed sharp-edged/rounded shape of the larger clasts.

 

The Herrera de los Navarras (Azuara impact) suevite 

suevite from Herrera de los Navarros, possibly carbonate melt matrix, Azuara impact structureFig. 17. Azuara impact structure: Polymictic basal breccia composed of Paleozoic and Mesozoic components (exposed near Herrera de los Navarros). The whitish zones of the matrix may be composed of decarbonized limestone or/and relics of carbonate melt.

 

The Monforte de Moyuela (Azuara impact) suevite 

suevite from Monforte de Moyuela, Azuara impact structureFig. 18. Azuara impact structure: Polymictic basal breccia. Note the flow texture and the grading of the components which are preferentially adjusted to the flow. Exposed near Monforte de Moyuela. The red color of many limestone clasts is a result of the impact heating.

 

The Barrachina (Rubielos de la Cérida impact) suevite

temporary quarry having uncovered suevite; Barrachina, Rubielos de la Cérida impact basin

Fig. 19. Temporary quarry set up in the Barrachina megabreccia, Rubielos de la Cérida impact basin. Here, large blocks of suevite were uncovered. Unfortunately, this impressive impact scenario completely incompatible with all Iberian Tertiary geologic setting was never internalized by the regional geologists.

suevite from the Rubielos de la Cérida impact basin; Barrachina quarryFig. 20. Rubielos de la Cérida suevite sampled from the quarry in Fig. 19. Silicate melt is concentrated in the whitish-yellowish, porous clasts.

one more suevite sample from the Rubielos de la Cérida impact basin; Barrachina quarryFig. 21. Rubielos de la Cérida suevite sampled from the quarry in Fig. 19. Like in the sample from Fig. 18 silicate melt is concentrated in the porous clasts.

 

Villafranca del Campo (Rubielos de la Cérida impact) suevites

suevite from the Rubielos de la Cérida impact basin, near Villafranca del Campo

Fig. 22. Suevite (basal breccia); Rubielos de la Cérida impact basin near Villafranca del Campo. Note the strongly disintegrated vesicular clasts.

suevite from the Rubielos de la Cérida impact basin, near Villafranca del Campo Fig. 23. One more variety of the Villafranca del Campo suevites, Rubielos de la Cérida impact basin. Note the strongly inhomogeneous texture of the breccia.

suevite from the Rubielos de la Cérida impact basin, near Villafranca del Campo Fig. 24. Suevite breccia with clasts from Buntsandstein, Muschelkalk and Keuper; Villafranca del Campo variety; Rubielos de la Cérida impact structure.

 

 Camañas (Rubielos de la Cérida basin) suevite

 Fig. 25. Suevite from the central-uplift chain, Rubielos de la Cérida impact basin. Camañas variety. 

 

Suevite from the Fuentes Calientes outcrop (Rubielos de la Cérida impact)

suevite from the Rubielos de la Cérida impact basin, near Fuentes CalientesFig. 26. Suevite (basal breccia); Rubielos de la Cérida impact basin near Fuentes Calientes (see outcrop image in Figs. 27, 28). This impressive outcrop with an educational geologic setting will in more detail be described soon. A prominent feature of this suevite are the highlighting lapilli inclusions.

suevite deposit (basal breccia) near Fuentes Calientes, Rubielos de la Cérida impact basinFig. 27. Suevite (basal breccia) near Fuentes Calientes exposing interbedding of breccia layers (marked in Fig. 28).

interbedding of suevite layers near Fuentes Calientes, Rubielos de la Cérida impact basin

Fig. 28. Interbedding of suevite (basal breccia) layers near Fuentes Calientes.

 

Escriche (Rubielos de la Cérida basin) suevite

Fig. 29. Suevite from near Escriche, south-eastern rim zone of the Rubielos de la Cérida impact basin. This suevite distinguishes by its varying lapillistone matrix and the few sharp-edged (Muschelkalk ?) fragments.

Suevites from near Olalla

Remarkable suevite (basal breccia) varieties are outcropping between Olalla and Fonfría in near contact with the large impact ejecta deposit of the Pelarda Formation in the northern rim zone of the Rubielos de la Cérida impact basin but also in near contact to the rim of the Azuara impact structure.

suevite from the rim region of the Rubielos de la Cérida impact basinFig. 30. Suevite (basal breccia); rim zone of the Rubielos de la Cérida basin near Olalla. Note the flow texture and the heavily shattered however coherent clasts.

suevite from the northern rim region, Rubielos de la Cérida impact basin, near Olallat structure near FuendetodosFig. 31. Suevite; rim zone of the Rubielos de la Cérida basin near Olalla.

suevite, variety 2, from the northern rim region, Rubielos de la Cérida impact basin, near Olallat structure near FuendetodosFig. 32. Suevite, rim zone Rubielos de la Cérida impact basin. Near Olalla. Note the flow texture and the fractured however coherent clasts proving high pressure on breccia emplacement.

suevite, variety 3, from the northern rim region, Rubielos de la Cérida impact basin, near Olallat structure near FuendetodosFig. 33. Suevite, basal breccia with Paleozoic and Mesozoic components; rim zone Rubielos de la Cérida impact basin. Near Olalla.

close-up of a suevite breccia, variety 4, Olalla outcrops, Rubielos de la CéridaFig. 34. Close-up of a suevite breccia from the outcrops near Olalla, Rubielos de la Cérida impact basin. The whitish parts of the matrix could be relics of carbonate melt.

suevite, variety 5, from the northern rim region, Rubielos de la Cérida impact basin, near Olallat structure near FuendetodosFig. 35. Suevite, variety 5,  rim zone Rubielos de la Cérida impact basin; near Olalla. Note the matrix dikelet penetrating the larger clast.

suevite, variety 6, from the northern rim region, Rubielos de la Cérida impact basin, near Olallat structure near FuendetodosFig. 36. Suevite, variety 6, rim zone Rubielos de la Cérida impact basin; near Olalla. Note the light crusts around most clasts pointing to some reaction between matrix and rock fragments. Also note again the dikelet traversing the largest clast.

suevite, variety 7, from the northern rim region, Rubielos de la Cérida impact basin, near Olallat structure near FuendetodosFig. 37. Suevite, variety 7, rim zone Rubielos de la Cérida impact basin; near Olalla.

suevite, variety 8, from the northern rim region, Rubielos de la Cérida impact basin, near Olallat structure near Fuendetodos

Fig. 38. Suevite, variety 8, rim zone Rubielos de la Cérida impact basin; near Olalla. The mostly monomictic breccia components in an allochthonous matrix are characterized by a distinct coherence of heavily fractured clasts pointing to high-pressure emplacement.